Reaction Process between Cobalt Tungstate and Chlorine
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چکیده
منابع مشابه
Reaction products of chlorine dioxide.
Inspection of the available literature reveals that a detailed investigation of the aqueous organic chemistry of chlorine dioxide and systematic identification of products formed during water disinfection has not been considered. This must be done before an informed assessment can be made of the relative safety of using chlorine dioxide as a disinfectant alternative to chlorine. Although trihal...
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The chlorite-iodide reaction is unusual because it is substrate-inhibited and autocatalytic. Because analytically pure ClO2 ion is not easily prepared, it was generated in situ from the rapid reaction between ClO2 and I-. The resulting overall reaction is multiphasic, consisting of four separable parts. Sequentially, beginning with mixing, these parts are the (a) chlorine dioxide-iodide, (b) ch...
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The kinetics of phenol oxidation with chlorine dioxide in different solvents (2 methylpropan 1 ol, ethanol, 1,4 dioxane, acetone, acetonitrile, ethyl acetate, dichloromethane, heptane, tetrachloromethane, water) was studied by spectrophotometry. In all solvents indicated, the reaction rate is described by an equation of the second order w = k[PhОН]•[ClO2]. The rate constants were measured (at 1...
متن کاملThe Reaction of Chlorine with Hydrogen.
The authors are indebted to Professor Charles Palache of Harvard University, Professor D. Jerome Fischer of the University of Chicago and Dr. T. L. Tanton of the Department of Mines of the Canadian Geological Survey, through whose efforts the rocks used in this investigation were obtained. 1 Rayleigh, Proc. Roy. Soc., 80, 575 (1908). 2Rayleigh, Nature, 123, 607 (1929). 3 See Harkins, P. R., 38,...
متن کاملHigh-Temperature Kinetics of the Reaction between Chlorine Atoms and Hydrogen Sulfide
The rate constant k1 for Cl + H2S has been measured over 290-914 K using the laser flash photolysis/resonance fluorescence technique. Atomic chlorine was generated by pulsed 193 nm photolysis of CCl4 and C6H5Cl and monitored by time-resolved resonance fluorescence at 130-140 nm. The data are summarized as k1 = (2.90 ± 0.10) × 10-11 exp(2.38 ± 0.11 kJ mol-1/RT) cm3 molecule-1 s-1 where the uncer...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1976
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.49.2633